World Library  

Add to Book Shelf
Flag as Inappropriate
Email this Book

A Thermodynamic Approach to Link Self-organization, Preferential Flow and Rainfall–runoff Behaviour : Volume 17, Issue 11 (01/11/2013)

By Zehe, E.

Click here to view

Book Id: WPLBN0004010924
Format Type: PDF Article :
File Size: Pages 26
Reproduction Date: 2015

Title: A Thermodynamic Approach to Link Self-organization, Preferential Flow and Rainfall–runoff Behaviour : Volume 17, Issue 11 (01/11/2013)  
Author: Zehe, E.
Volume: Vol. 17, Issue 11
Language: English
Subject: Science, Hydrology, Earth
Collections: Periodicals: Journal and Magazine Collection, Copernicus GmbH
Publication Date:
Publisher: Copernicus Gmbh, Göttingen, Germany
Member Page: Copernicus Publications


APA MLA Chicago

Kleidon, A., Blume, T., Westhoff, M., Zehe, E., Scherer, U., & Ehret, U. (2013). A Thermodynamic Approach to Link Self-organization, Preferential Flow and Rainfall–runoff Behaviour : Volume 17, Issue 11 (01/11/2013). Retrieved from

Description: Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany. This study investigates whether a thermodynamically optimal hillslope structure can, if existent, serve as a first guess for uncalibrated predictions of rainfall–runoff. To this end we propose a thermodynamic framework to link rainfall–runoff processes and dynamics of potential energy, kinetic energy and capillary binding energy in catchments and hillslopes. The starting point is that hydraulic equilibrium in soil corresponds to local thermodynamic equilibrium (LTE), characterized by a local maximum entropy/minimum of free energy of soil water. Deviations from LTE occur either due to evaporative losses, which increase absolute values of negative capillary binding energy of soil water and reduce its potential energy, or due to infiltration of rainfall, which increases potential energy of soil water and reduces the strength of capillary binding energy. The amplitude and relaxation time of these deviations depend on climate, vegetation, soil hydraulic functions, topography and density of macropores. Based on this framework we analysed the free energy balance of hillslopes within numerical experiments that perturbed model structures with respect to the surface density of macropores. These model structures have been previously shown to allow successful long-term simulations of the water balances of the Weiherbach and the Malalcahuello catchments, which are located in distinctly different pedological and climatic settings. Our findings offer a new perspective on different functions of preferential flow paths depending on the pedological setting. Free energy dynamics of soil water in the cohesive soils of the Weiherbach is dominated by dynamics of capillary binding energy. Macropores act as dissipative wetting structures by enlarging water flows against steep gradients in soil water potential after long dry spells. This implies accelerated depletion of these gradients and faster relaxation back towards LTE. We found two local optima in macropore density that maximize reduction rates of free energy of soil water during rainfall-driven conditions. These two optima exist because reduction rates of free energy are, in this case, a second-order polynomial of the wetting rate, which implicitly depends on macroporosity. An uncalibrated long-term simulation of the water balance of the Weiherbach catchment based on the first optimum macroporosity performed almost as well as the best fit when macroporosity was calibrated to match rainfall–runoff. In the Malalcahuello catchment we did not find an apparent optimum density of macropores, because free energy dynamics of soil water during rainfall-driven conditions is dominated by increases of potential energy. Macropores act as dissipative drainage structures by enhancing export of potential energy. No optimum macropore density exists in this case because potential energy change rates scale linearly with the wetting rate. We found, however, a distinguished macroporosity that assures steady-state conditions of the potential energy balance of the soil, in the sense that average storage of potential energy is compensated by average potential energy export. This distinguished macroporosity was close to the value that yielded the best fit of rainfall–runoff behaviour during a calibration exercise and allowed a robust estimate of the annual runoff coefficient. Our findings are promising for predictions in ungauged catchments (PUB) as the optimal/distinguished model structures can serve as a first guess for uncalibrated predictions of rainfall–runoff. They also offer an alternative for classifying catchments according to their similarity of the free energy balance components.

A thermodynamic approach to link self-organization, preferential flow and rainfall–runoff behaviour

Beven, K. and Clarke, R. T.: On the variation of infiltration into a soil matrix containing a population of macropores., Water Resources Res., 22, 383–385, 1986.; Beven, K. and Germann, K.: Macropores and water flow in soils, Water Resources Res., 18, 1311–1325, 1982.; Blume, T.: Hydrological processes in volcanic ash soils: measuring, modelling and understanding runoff generation in an undisturbed catchment, Ph. D., Institut für Geoökologie, Universität Potsdam, Potsdam, 153 pp., 2008.; Blume, T., Zehe, E., and Bronstert, A.: Rainfall-runoff response, event-based runoff coefficients and hydrograph separation, Hydrolog. Sci. J., 52, 843–862, 2007.; Blume, T., Zehe, E., and Bronstert, A.: Investigation of runoff generation in a pristine, poorly gauged catchment in the Chilean Andes II: Qualitative and quantitative use of tracers at three spatial scales, Hydrol. Process., 22, 3676–3688, doi:10.1002/hyp.6970, 2008a.; Blume, T., Zehe, E., Reusser, D. E., Iroume, A., and Bronstert, A.: Investigation of runoff generation in a pristine, poorly gauged catchment in the Chilean Andes I: A multi-method experimental study, Hydrol. Process., 22, 3661–3675, doi:10.1002/hyp.6971, 2008b.; Blume, T., Zehe, E., and Bronstert, A.: Use of soil moisture dynamics and patterns at different spatio-temporal scales for the investigation of subsurface flow processes, Hydrol. Earth Syst. Sci., 13, 1215–1233, doi:10.5194/hess-13-1215-2009, 2009.; Brocca, L., Morbidelli, R., Melone, F., and Moramarco, T.: Soil moisture spatial variability in experimental areas of central Italy, J. Hydrol., 333, 356–373, 2007.; Bull, L. J. and Kirkby, M. J.: Gully processes and modelling, Progr. Phys. Geogr., 21, 354–374, 1997.; Celia, M. A. and Bouloutas, E. T.: A general mass-conservative numerical solution for the unsaturated flow equation, Water Resources Res., 26, 483–1496, 1990.; Dewar, R. C.: Maximum Entropy Production as an Inference Algorithm that Translates Physical Assumptions into Macroscopic Predictions: Dont Shoot the Messenger, Entropy, 11, 931–944, doi:10.3390/e11040931, 2009.; Dietrich, W. E., and Perron, J. T.: The search for a topographic signature of life, Nature, 439, 411 – 418, 2006.; Dooge, J. C. I.: Looking for hydrological laws, Water Resour. Res., 22, 46S–58S, 1986.; Ehlers, W., Avci, O., and Markert, B.: Computation of Slope Movements Initiated by Rain-Induced Shear Bands in Small-Scale Tests and In Situ, Vadose Zone J., 10, 512–525, doi:10.2136/vzj2009.0156, 2011.; Harman, C. and Troch, P. A.: Darwinian hydrology: can the methodology Charles Darwin pioneered help hydrologic science?, Hydrol. Earth Syst. Sci. Discuss., 10, 6407–6444, doi:10.5194/hessd-10-6407-2013, 2013.; Howard, A. D.: Theoretical model of optimal drainage networks, Water Resour. Res., 26, 2107–2117, 1990.; Klaus, J. and Zehe, E.: Modelling rapid flow response of a tile drained field site using a 2D-physically based model: assessment of equifinal model setups, Hydrol. Process., 24, 1595–1609, doi:10.1002/hyp.7687, 2010.; Klaus, J. and Zehe, E.: A novel explicit approach to model bromide and pesticide transport in connected soil structures, Hydrol. Earth Syst. Sci., 15, 2127–2144, doi:10.5194/hess-15-2127-2011, 2011.; Kleidon, A.: How does the earth system generate and maintain thermodynamic disequilibrium and what does it imply for the future of the planet? Philos. T. R. Soc. A, 370, 1012–1040, doi:10.1098/rsta.2011.0316


Click To View

Additional Books

  • Multi-criteria Validation of Artificial ... (by )
  • Study of Frequency Pattern of Coherent T... (by )
  • Accessible Integration of Agriculture, G... (by )
  • Comment on Biotic Pump of Atmospheric Mo... (by )
  • Comparing Soil Moisture Retrievals from ... (by )
  • Errata : Volume 8, Issue 5 (30/11/-0001) 
  • Transport at Basin Scales: 2. Applicatio... (by )
  • Geodynamical Processes in the Channel Co... (by )
  • Calibration of a Crop Model to Irrigated... (by )
  • Uncertainty Analysis of Hydrological Ens... (by )
  • Climate Change and Sectors of the Surfac... (by )
  • Assessing Impacts of Climate Change, Sea... (by )
Scroll Left
Scroll Right


Copyright © World Library Foundation. All rights reserved. eBooks from Hawaii eBook Library are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.